If I don't use all this tape immediately, wilI it still be good beyond its specified 5-year shelf life?

Yes, it should be. Mine has always lasted longer than 5 years in all types of weather.

How well does this stick to aluminum and steel?

not sure we use it for Polo Sticks and boots

The pink option says 100 rolls both in the title description and in the 2nd product photo. Is it 100 rolls or 1 roll?

Live dangerously you might get 100 rolls and turn into an ebay millionaire.

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